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2.
HAZARDS IDENTIFICATION |
Emergency Overview
Form: Liquid
Colour: Clear to blue
Odour: Odourless
Warning Statements
WARNING!
Causes skin irritation
Elevated processing temperatures may cause release of toxic vapours which
are harmful if inhaled.
Potential Health Effects
| Likely routes of exposure: |
Inhalation
Eye and skin contact |
| Eye contact: |
No more than slightly irritating to eyes. |
| Skin contact: |
Highly irritating to skin.
No more than slightly toxic if absorbed. |
| Inhalation: |
Elevated processing temperature may cause release of
vapours which are harmful if inhaled. |
| Ingestion: |
No more than slightly toxic if swallowed.
Significant adverse health effects are not expected to develop if
only small amounts (less than a mouthful) are swallowed.
Refer to Section 11 for toxicological
information
|
|
|
3.
COMPOSITION/INFORMATION ON INGREDIENTS |
| Components |
CAS No. |
Avgerage
Concentration |
Concentration
Range |
Units |
| 2-ethylhexyl diphenyl phosphate |
1241-94-7 |
|
>90.0 |
% |
| bis(2-ethylhexyl) phenyl phosphate |
16368-97-1 |
|
<5.0 |
% |
| triphenyl phosphate |
115-86-6 |
|
<5.0 |
% |
|
4.
FIRST AID MEASURES
| If in eyes: |
Immediate first aid is not likely to be required.
This material can be removed with water. |
| If on skin: |
Immediately flush the area with plenty of water.
Remove contaminated clothing.
Get medical attention.
Wash clothing before reuse. |
| If inhaled: |
Remove patient to fresh air.
If not breathing, give artificial respiration.
If breathing is difficult give oxygen.
Remove material from eyes, skin and clothing. |
| If swallowed: |
Immediate first aid is not likely to be required.
A physician or Poison Control Center can be contacted for advise.
Wash heavily contaminated clothing before reuse.
|
|
|
| 5.
FIRE FIGHTING MEASURES |
| Fire point: 244°C |
Cleveland Open Cup |
| Hazardous products of combustion: |
Carbon monoxide (CO); Carbon Dioxide; Soot; Smoke;
Phosphorus oxides (PxOy) |
| Extinguishing media: |
Water spray, foam, dry chemical, or carbon dioxide |
| Unusual fire and explosion hazards: |
None known |
| Fire fighting equipment: |
Firefighters and others exposed wear self-contained
breathing apparatus.
Equipment should be thoroughly decontaminated after use.
|
|
| 6.
ACCIDENTAL RELEASE MEASURES |
| Personal precautions: |
Use personal protection recommended in
Section 8. |
| Environmental precautions: |
Keep out of drains and water courses. |
| Methods for cleaning up: |
Contain large spills with dikes and transfer the
material to appropriate containers for reclamation or disposal.
Absorb remaining material or small spills with an inert material
and then place in a chemical waste container. |
Refer to Section 13
for disposal information and Sections 14 and 15 for reportable quantity
information.
|
| 7.
HANDLING AND STORAGE |
|
Handling
Avoid contact with eyes, skin and clothing.
Avoid breathing vapour or mist.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
Emptied containers retain vapour and product residue.
Observe all recommended safety precautions until container is cleaned,
reconditioned or destroyed. Do not reuse this container.
Storage
Temperature: 0-79°C
General: Store in a
cool dry place, away from foodstuffs and acids.
Stable under normal conditions of handling and storage.
|
| 8.
EXPOSURE CONTROLS/PERSONAL PROTECTION |
| Airbourne exposure limits: |
(ml/m3 = ppm) |
| MCS® -2361 |
No specific occupational exposure limit has been established. |
| Triphenyl phosphate |
ACGIH TLV: 3mg/m3; ; 8 hr. TWA
OSHA PEL: 3mg/m3; ;8 hr. TWA
Mexican OEL: 3mg/m3; ; 8 hr. TWA
Mexican OEL: 6mg/m3; ; 15 min STEL TWA |
| Eye protection: |
Does not cause significant eye irritation or eye
toxicity requiring special protection.
Use good industrial practice to avoid eye contact. |
| Hand protection: |
Wear chemical resistant gloves.
Consult the glove/clothing manufacturer to determine the
appropriate type of glove/clothing for a given application. |
| Body protection: |
Wear suitable protective clothing.
Wear full protective clothing if exposed to splashes.
Consult the glove/clothing manufacturer to determine the
appropriate type of glove/clothing for a given application.
Wash contaminated skin promptly.
Launder contaminated clothing and clean protective equipment
before reuse.
Wash thoroughly after handling.
Have safety shower available at locations where skin contact can
occur. |
| Respiratory protection: |
Avoid breathing vapour or mist.
Use approved respiratory protection equipment when airborne
exposure limits are exceeded.
Consult the respirator manufacturer to determine the appropriate
type of equipment for a given application.
Observe respirator use limitations specified by the manufacturer. |
| Ventilation: |
Provide natural or mechanical ventilation to control
exposure levels below airborne exposure limits.
If practical, use local mechanical exhaust ventilation at sources of
air contamination such as processing equipment. |
Components referred to
herein may be regulated by specific Canadian provincial legislation.
Please refer to exposure limits legislated for the province in which the
substance will be used.
|
| 9.
PHYSICAL AND CHEMICAL PROPERTIES |
| Flash point: |
229°C
Cleveland Open Cup |
| Specific Gravity: |
1.085-1.095 @ 25°C |
| Boiling point: |
375°C
@ 1,013 hPa |
| Water
solubility: |
negligible |
| Viscosity: |
9.8
- 10.6 mPa.s @ 38°C |
| Vapour
density (air=1): |
>1 |
|
| NOTE:
These physical data are typical values based on material tested but may
vary from sample to sample. Typical values should not be construed as a
guaranteed analysis of any specific lot or as specifications for the
product.
|
| 10.
STABILITY AND REACTIVITY |
| Conditions to avoid: |
Elevated temperatures |
| Materials to avoid: |
Contact with strong oxidizing agents |
| Hazardous reactions: |
Hazardous polymerization does not occur |
| Decomposition: |
Decomposition occurs at elevated temperatures |
| Decomposition temperature: |
79°C
|
| Hazardous decomposition products: |
Phosphorus oxides (PxOy) |
|
| 11.
TOXICOLOGICAL INFORMATION |
|
This product has not been tested for toxicity, but data
obtained on similar products are summarized below:
Acute animal toxicity data:
| Oral: |
LD50, rat, >15,800 mg/kg, practically nontoxic
following oral administration. |
| Dermal: |
LD50, rabbit, >7,940 mg/kg, practically
nontoxic after skin application in animal studies. |
| Inhalation: |
LC50, mouse, 3 mg/l vapour
LC50, rat, >4.8 mg/l |
| Eye irritation: |
Rabbit, practically non-irritating to eyes, 24 h |
| Skin irritation: |
Rabbit, slightly irritating to skin, 24h |
| Skin sensitization: |
Human experience, predictive patch testing on human
volunteers produced primary irritation but no allergic skin
reactions. |
| Repeat dose toxicity: |
Rat, diet, 52 weeks, produced effects
on body weight, serum enzymes and/or organ weights in repeat dose
studies.
Dog, diet, 52 weeks, produced effects on body weight,
serum enzymes and/or organ weights in repeat dose studies. |
| Neurotoxicity: |
Chicken, gavage, acute, no adverse treatment related
effects. |
| Developmental toxicity: |
Rat, diet, no effects on offspring observed in
laboratory animals in the presence of maternal toxicity. |
| Mutagenicity: |
The active ingredient generally produced no genetic
changes in standard tests using animal, bacterial or yeast cells. |
| Components: |
|
| Data from Solutia studies
and/or the available scientific literature on the components of
this material which have been identified as hazardous chemicals
under the criteria of the OSHA Hazard Communication Standard (29
CFR 1910.1200) or the Canadian Hazardous Products Act are
discussed below if present: |
2-ethylhexyl diphenyl
phosphate |
Practically nontoxic following oral administration.
Practically nontoxic after skin application in animal studies.
Practically non irritating to eyes (rabbit).
Practically non irritating to skin (rabbit).
Practically nontoxic based on animal inhalation exposure studies.
Predictive patch testing on human volunteers did not produce
irritation or sensitization.
Produced effects on body weight, serum enzymes and/or organ
weights in repeat dose studies.
No delayed neurotoxicity was observed in animal models.
No effects on offspring observed in laboratory animals in the
presence of maternal toxicity.
The weight of the evidence indicates that this material is not
mutagenic in in-vitro assays.
The weight of the evidence indicates that this material is not
mutagenic in in-vivo assays. |
| triphenyl phosphate |
Practically nontoxic following oral administration.
Practically nontoxic after skin application in animal studies.
Practically non irritating to eyes (rabbit).
Practically non irritating to skin (rabbit).
No delayed neurotoxicity was observed in animal models.
Not carcinogenic.
No birth defects were noted in rats given the active ingredient
orally during pregnancy.
The weight of the evidence indicates that this material is not
mutagenic in in-vitro assays.
Produced cholinesterase inhibition (brain, blood cell, and/or
plasma) without signs of overt enzyme inhibition. |
12. ECOLOGICAL INFORMATION
Solutia has not conducted environmental toxicity or
biodegradation studies with this material.
13. DISPOSAL
CONSIDERATIONS
| US EPA RCRA Status: |
This material when discarded may be a hazardous
waste as that term is defined by the Resource Conservation and
Recovery Act (RCRA), 40 CFR 261.24 due to its toxicity
characteristic. This material should be analyzed in accordance
with Method 1311. |
| Disposal considerations: |
Recycle
Incineration |
| Miscellaneous advice: |
This product meets the criteria for a synthetic
used oil under the U.S. EPA Standards for the Management of Used
Oil (40 CFR 279.) Those standards govern recycling and disposal
in lieu of 40 CFR 260-272 of the Federal hazardous waste program
in states that have adopted these used oil regulations. Consult
your attorney or appropriate regulatory official to be sure
these standards have been adopted in your state. Recycle or burn
in accordance with the applicable standards. This product should
not be dumped, spilled, rinsed or washed into sewers or public
waterways.
|
|
14. TRANSPORT INFORMATION
The data provided in this section is for information only.
Please apply the appropriate regulations to properly classify your
shipment for transportation.
US DOT
| Proper shipping name: |
Environmentally Hazardous Substance, Liquid, N.O.S.
triphenyl phosphate |
| Hazard Class: |
9 |
| Hazard Identification number: |
UN3082 |
| Packing Group: |
Packing Group III |
| Transport Label: |
Class 9 |
| Special Provisions: |
This material meets the definition of a marine
pollutant. |
| Other: |
Applies ONLY to shipments in bulk or via inland
water transportation. |
| Canadian TDG |
|
| Special provisions: |
This material meets the definition of a marine
pollutant. |
| Other: |
Not regulated for transport.
|
| 15.
REGULATORY
INFORMATION |
| All components are on the following
inventories: |
U.S. TSCA, EU EINECS, Canadian DSL,
Australian AICS |
| Canadian WHMIS class.: |
D2(B)-Materials Causing Other Toxic
Effects |
| SARA Hazard Notification: |
Hazard Categories Under Title III Rules
(40 CFR 370): Immediate |
| |
Section 302 Extremely Hazardous
Substance: Not applicable |
| |
Section 313 Toxic Chemical:
Not applicable |
| CERCLA Reportable Quantity: |
Not applicable |
|
This product has been classified in accordance with the hazard
criteria of the Canadian Controlled Products Regulation and the
MSDS contains all the information required by the Canadian
Controlled Products Regulation. Refer to Section 11 for OSHA/HPA
Hazardous Chemical(s) and Section 13 for RCRA classification.
Safety data sheet also created in accordance with Brazilian law
NBR 14725
|
| 16.
OTHER
INFORMATION |
| Product use: |
Hydraulic fluids and additives |
| Reason for revision: |
Routine review and
update |
| Suggested NFPA Rating: |
Health 1; Fire 1; Reactivity 0 |
| Suggested HMIS Rating: |
Health 1; Fire 1; Reactivity 0;
Additional Information G |
|
|
| Prepared by the Solutia
Hazard Communication Group. Please consult Solutia at 314-674-6661 if further
information is needed.
|
| Although the information
and recommendations set forth herein (hereinafter
"Information") are presented in good faith and believed
to be correct as of the date hereof, Solutia Inc. makes no
representations as to the completeness or accuracy thereof.
Information is supplied upon the condition that the persons
receiving same will make their own determination as to its
suitability for their purposes prior to use. In no event will
Solutia Inc. be responsible for damages of any nature whatsoever
resulting from the use of or reliance upon Information. NO
REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER
NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE
PRODUCT TO WHICH INFORMATION REFERS. |
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